OCCUPATION AND HEALTH ›› 2025, Vol. 41 ›› Issue (12): 1625-1629.

• Treatise • Previous Articles     Next Articles

Simultaneous determination of eight herbicides and plant growth regulators in drinking water by ion chromatography

MA Xiaoman1, SHI Hongmei2, LI Yunbing1, ZHANG Laiying1, GAO Lihong3, WANG Yujiang1   

  1. 1. Department of Physical and Chemical Testing, Fengtai Center for Diseases Control and Prevention, Beijing 100070, China;
    2. School of Public Health, Hebei Medical University, Shjiazhuang, Hebei 050017, China;
    3. Thermo Fisher Scientific Inc, Beijing 100013, China
  • Received:2025-03-25 Revised:2025-04-02 Published:2025-12-11
  • Contact: WANG Yujiang,Chief technician,E-mail:yujiangwang@126.com

Abstract: Objective To develop a detection method for simultaneous determination of eight herbicides(including 2,4-D,fosamine,aminomethylphosphonic acid,glufosinate,ethephon,glyphosate,glyphosine,and bentazone) and plant growth regulators in drinking water by ion chromatography,which has a simple pretreatment process and only requires common reagents. Methods The water sample is sequentially filtered through a 0.2 μm microporous membrane and a Ba/Ag/H cartridge before being introduced into the system. The effective separation is achieved on an IonPac AS19 chromatographic column using a 2-60 mmol/L potassium hydroxide gradient elution program. After the background signal is reduced by a suppressor,the analytes are detected by a conductivity detector. Results The eight analytes exhibit excellent linearity within the concentration range of 0.002-0.200 mg/L(0.005-0.200mg/L),with correlation coefficients(r) all >0.999. The method demonstrates detection limits ranging 0.000 2-0.003 6 mg/L and quantification limits ranging 0.000 6-0.011 1 mg/L. At low,medium,and high spiked concentration levels,the recovery rates range from 94.3% to 108.6%,with relative standard deviations(RSD) between 0.592% and 4.425%(n=7). Compared with the national standard method,the detection results showed no statistically significant difference(P>0.05). Conclusion This method is characterized by its simplicity of operation,effective separation,and satisfactory accuracy,precision and sensitivity,making it suitable for routine monitoring of drinking water.

Key words: Ion chromatography, Drinking water, Herbicide, Plant growth regulators, Simultaneous determination

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